Crystal System and Their Identification

The crystallographic axes are the imaginary lines that we can draw within the crystal lattice. These crystal axis than works as the coordinate system within the crystal. These are well defined lines for the crystals.

  • A crystal may have three or more crystal axes, and the angle between them can also varies.

On the basis of number of crystal axes and mutual relationship between them we define a crystal system

Crystal systemCrystal axes Characteristic symmetry elementsNo. of classes
Isometric or Cubic systema1 = a2 = a3
a1 ^ a2 ^ a3 = 900
4 axes of III fold symmetry5
Tetragonal systema1 = a2 ≠ c
a1 ^ a2 ^ c = 900
unique IV fold axes symmetry or VII fold axis of inversion7
Hexagonal systema1 = a2 = a3 ≠ c
a ^ c = 900
hexagonal division (unique VI fold axis or inversion)
trigonal division (unique III fold axis or inversion)
hexagonal division -7
trigonal division – 5
Orthorhombic systema ≠ b ≠ c
a ^ b ^ c= 900
3 axis of II fold symmetry3
Monoclinic systema ≠ b ≠ c
a ^ c ≠ 900, b ^ c = 900
1 axis of II fold symmetry3
Triclinic systema ≠ b ≠ c
a ^ b ^ c ≠ 900
no axis or plane of symmetry2
  1. Cubic system : There are three axes. All the axes are perpendicular to each other and interchangeable.
  2. Tetragonal system : There are three axes. The two horizontal axes are of equal length and can be interchanged. The vertical axis can be longer or shorter. All the axes are perpendicular to each other.
  3. Hexagonal system :
    • Hexagonal division – horizontal axes are equal and are interchangeable. all horizontal axes are perpendicular to the vertical axes.
    • Trigonal division –
  4. Orthorhombic system : There are three axes. all are of unequal length but are mutually perpendicular to each other.
  5. Monoclinic system : There are three axes. all are of unequal length. a-axis is not perpendicular to vertical . b-axis is perpendicular to the c axis.
  6. Triclinic system :There are three axes. all are of unequal length. none of them are perpendicular to each other.
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