There are three elements of crystal forms. The face, edge and solid angle.
- Faces – Faces are the external expression of the internal atomic structure. Faces can be ‘like’ if they have same properties and ‘unlike’ if they have different properties.
- Edges – The line created by the intersection of two adjacent faces is termed as edge.
- Solid angles – Solid angle is a point created by the intersection of three or more than three planes.
Forms – It is a group of faces which have a like positions with respect to the crystallographic orientations. Forms may be classified in the following three ways –
1st way | 2nd way | 3rd way |
Simple form – when a crystal is made up of all alike faces the form is called simple form. EX- Cube, Octahedron etc. | Open form – These are the form which doesn’t enclose the space all by themselves. EX- pinacoid, prisms etc. | General form – It is one in which the indices are unrestricted in magnitudes. |
Combination form – when a crystal is made up of two or more simple form, it is called combination form EX- combination of prisms and pinacoid. | Closed form – These are the form which can enclose the space all by themselves. EX- pyramid etc. | Special form – It is one in which there is only one possible value of indices. EX- octahedron (111) |
Restricted form – when the forms are neither special nor general but some part of their indices are fixed and some part is variable, the resulted form is called restricted form. EX- Prisms (hkl) [l is always zero], trisoctahedron of cubic system [h must always equal to k] |
besides above forms can also be classified in four important types –
- Holohedral forms – These forms exhibits the highest degree of symmetry possible in a system.
- Hemihedral forms – These forms show half the number of faces required for the full symmetry of the system. EX- tetrahedron is the hemihedralform of octahedron.
- Hemi-morphic forms – This form have unlike faces at the different ends of the axis of symmetry. This axis is called polar axes.
- Thus half of the faces of holohedral forms are grouped at the one end of the axis and none at the other end.
- This forms lack centre of symmetry.
- Tetartohedral forms – They show only a quarter of the number of faces of the corresponding holohedral form.
- These forms have neither plane nor centre of symmetry.
- Enantiomorphic forms – These forms occur in two positions which are mirror image to each other.
- They can not be converted into each other by ay means of rotation.
- They do not have either plane or centre of symmetry.
Common crystal forms
- Pedion – it has only one face
- Pinacoid – it is an open form, consisting of two faces which cuts one crystallographic axis and parallel ot the other two axis.
- Prisms – it is an open form, consisting of four faces which are parallel to the vertical axis and cuts one or more horizontal axis at equal or unequal lengths
- Pyramids – it is an closed form, consisting of eight faces which always cut the vertical axis and one or more horizontal axis at equal or unequal lengths
- Domes – it is an open form but intermediate between the prisms and pyramids, as it cuts vertical axis and one horizontal axis. These are also called as horizontal prisms.
- Dimetral prisms – it is formed by the combination of three pinacoid which together becomes closed form. They only occurs in the orthorhombic, monoclinic and triclinic systems.