Mica Group

The mica group of minerals crystallizes in the monoclinic system. They are phyllosilicates with their general formula as – X2Y4-6Z8O20[OH,F]4

Where, X = K, Na, Ba, Ca Y = Al, Mg, Fe+2, Li, Cr, Mn, Zn Z = Si, Al, Fe+3

  • They are hydrated alumino-silicates of K, Na, Li and Mg or Fe as darker members.
  • Mica minerals are generally found in all felsic rocks and makes an important part in pegmatites.
  • They are highly conductor of heat and bad conductor of electricity.

STRUCTURE

Structurally micas can be divided into the two groups –

  1. The Di-octahedral sheet silicates where each O or OH ion is surrounded by 2 tri-valent cations, usually Al+3 [muscovite]
  2. The tri-octahedral sheet silicates where each O or OH ion is surrounded by 3 di-valent cations, like Mg+2, Fe+2

These sheets are jointed by the cations like K be wan der vaals bond giving a basal cleavage.

important minerals –

  • Phlogopite – KMg3Si3AlO10[OH]2
  • Biotite – K[Fe, Mg]3Si3AlO10[OH]2
  • Muscovite – KAl2Si3AlO10[OH]2
  • Lapidolite – KLi2AlSi3AlO10[OH]2
  • Paragonite -NaAl2Si3AlO10[OH]2
  • Variety –
    • Fuschsite is Cr- bearing mica
    • Roscoelite is Vanadium bearing muscovite
    • Vermiculite is altered biotite

physical and optical properties

physical properties

  1. color – white for muscovite and brown for biotite
  2. form – tabular
  3. hardness – 2-3
  4. specific gravity – low
  5. lusture – vitreous
  6. special property – elasticity, transparency

optical properties

  1. color- muscovite is colorless, biotite is brown
  2. RI- high
  3. Birefringence – strong
  4. extinction – parallel

Mode of occurrence –

  • muscovite occurs in acid igneous rocks while biotite can ocur in all igneous rocks
  • they are also found in sedimentary rocks
  • they are vary common in the schists and gneises.
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